Influence of Fuel Characteristics on Fluidized Bed Combustion of Woody Biomass

Yazarlar

Zuhal Akyürek
Afşin Güngör

Özet

This research evaluates the combustion performance, stack gas emissions, and ash deposition behavior of bamboo wood waste as a sustainable biomass fuel in a 1 MWth bubbling fluidized bed combustor (BFBC) operating at 800 °C. A mathematical modeling approach assuming chemical equilibrium and isothermal operation was employed to calculate flue gas species, including O2, N2, CO2, H2O, SO2, and NOx. The model predictions reveal that NOx and dust emissions stay safely below the statutory limits set by the European Union Medium Combustion Plant Directive (MCPD), whereas SO2 emissions surpass the regulatory threshold, demonstrating that sulfur-binding additives like limestone are required during operation. In addition, the ash properties were systematically analyzed using key empirical indicators: the Alkali Index, Bed Agglomeration Index, Base to Acid Ratio, and Corrosion Index. Due to high potassium and alkali content in the fuel ash, bamboo wood exhibits a severe tendency toward slagging, fouling, and bed agglomeration, as indicated by an Alkali Index over 0.34 kg/GJ, an Agglomeration Index below 0.15, and a Base to Acid Ratio of 0.55. Furthermore, the calculated Corrosion Index of 3.09 highlights potential high-temperature corrosion hazards. To mitigate these operational challenges, feedstock leaching, co-firing with traditional fossil fuels, or adding specific chemical additives should be implemented.

Referanslar

World Bioenergy Association, “Global Bioenergy Statistics 2020”, http://www.worldbioenergy.org/uploads/201210%20WBA%20GBS%202020.pdf

Akyürek Z. Sustainable Valorization of Animal Manure and Recycled Polyester: Co-pyrolysis Synergy, Sustainability 2019, 11 (8): 2280, 2019. Doi: 10.3390/su11082280

Khan AA, Jong W, Jansens PJJ, Spliethoff, HS. Biomass combustion in fluidized bed boilers: Potential problems and remedies. Fuel Processing Technology 2009; 90(1): 21-50. https://doi.org/10.1016/j.fuproc.2008.07.012

Bhattacharya SC, Salam PA, Pham HL, Ravindranath NH. Sustainable biomass production for energy in selected Asian countries, Biomass and Bioenergy 2003; 25: 471-482. https://doi.org/10.1016/S0961-9534(03)00085-0

Wong SL, Ngadi N, Abdullah TAT, Inuwa IM. Current state and future prospects of plastic waste as source of fuel: A review. Renewable and Sustainable Energy Reviews 2015; 50: 1167-1180. https://doi.org/10.1016/j.rser.2015.04.063

Akyürek Z, Ullah A, Sulaiman S.A., Gungör A, The Prediction of Asf Related Issues during Agro-waste Combustion in Fluidized Beds, New Horizons in Techno-Science, Akademisyen Publishing, ISBN:978-605-258-763-8, pp. 39 -50, 2019.

Gogebakan Z, Co-firing Biomass and Coal in Bubbling Fluidized Bed Combustors”, PhD Dessertation, 2007, Middle East Technical University.

Farooq S, Pans MA, Afilaka DT, Liu CSH, Experimental investigation of woody and non-woody biomass combustion in a bubbling fluidised bed combustor focusing on gaseous emissions and temperature profiles, Energy 2017, 141: 2069-2080. https://doi.org/10.1016/j.energy.2017.11.118.

Werther, J, Saenger, M, Hartge, EU, Ogada, T, Siagi, Z. Combustion of agricultural residues, Progress in Energy and Combustion Science 2000; 26: 1–27. PII: S0360-1285(99)00005-2

Tobiasen L, Skytte R, Pedersen LS, Pedersen ST, Lindberg MA. Deposit characteristic after injection of additives to a Danish straw-fired suspension boiler. Fuel Process. Technol. 2007, 88: 1108-1117. https://doi.org/10.1016/j.fuproc.2007.06.017

Jensen PA, Stenholm M, Hald P. Deposition investigation in straw-fired boilers”, Energy Fuels 1997, 11: 1048-1055.

Lapuerta M, Acosta A, Pazo A. Fouling deposits from residual biomass with high sodium content in power plants. Energy Fuels 2015, 29: 5007-5017.

Li G, Li S, Xu X, Huang Q, Yao Q, Dynamic behavior of biomass ash deposition in a 25 kW one-dimensional down-fired combustor, Energy Fuels 2014, 28: 219-227.

Deng L, Jin X, Long J, Che D. Ash deposition behaviors during combustion of raw and water washed biomass fuels. Journal of the Energy Institute 2019, 92(4): 959-970. https://doi.org/10.1016/j.joei.2018.07.009

Namkung H, Lee YJ, Park H, Song GS, Choi JW, Kim JG, Park SJ, Park JC, Kim HT, Choi YC. Influence of herbaceous biomass ash pre-treated by alkali metal leaching on the agglomeration/sintering and corrosion behaviors. Energy 2019; 187: 115950. https://doi.org/10.1016/j.energy.2019.115950

Yao XW, Xu KL, Yan F, Liang Y. The influence of ashing temperatures on ash fouling and slagging characteristics during combustion of biomass fuels. Bioresources 2017; 12: 1593-1610. https://doi.org/10.15376/biores.12.1.1593-1610

Billen P, Creemers B, Costa J, Van Caneghem J, Vandecasteele C, Coating and melt induced agglomeration in a poultry litter fired fluidized bed combustor, Biomass and Bioenergy 2014; 71-79. https://doi.org/10.1016/j.biombioe.2014.07.013

Scala F, Salatino P, Chirone R. Fluidized bed combustion of a biomass char (Robinia pseudoacacia). Energy and Fuels 2000; 14: 781-790.

Purbasaria A, Samadhia TW, Bindar Y. Thermal and Ash Characterization of Indonesian Bamboo and Its Potential for Solid Fuel and Waste Valorization. Int. Journal of Renewable Energy Development 2016, 5 (2): 95-100.

Gómez-Hernández J, Serrano D, Soria-Verdugo A, Sánchez-Delgado S, Agglomeration detection by pressure fluctuation analysis during Cynara cardunculus L. gasification in a fluidized bed”, Chem Eng J 2016, 284: 640-649. Doi:10.1016/j.cej.2015.09.044.

Smith AM, Ross AB, The Influence of Residence Time during Hydrothermal Carbonisation of Miscanthus on Bio-Coal Combustion Chemistry, Energies 2019, 12: 523. Doi:10.3390/en12030523

Vamvuka D, Zografos D, Alevizos G, Control methods for mitigating biomass ash-related problems in fluidized beds, Bioresource Technology 2008, 99: 3334-3344. https://doi.org/10.1016/j.biortech.2007.07.049

Dayton DC, Jenkins BM, Turn SQ, Bakker RR, Williams RB, Belle-Oudry D, Hill LM, Release of inorganic constituents from leached biomass during thermal conversion, Energy and Fuels 1999, 13: 860. https://doi.org/10.1021/ef980256e.

Niu Y, Zhu Y, Tan H, Hui S, Jing Z, Xu W, Investigations on biomass slagging in utility boiler: criterion numbers and slagging growth mechanisms, Fuel Process Technol 2014, 128: 499-508.

Morris JD, Daood SS, Chilton S, Nimmo W, Mechanisms and mitigation of agglomeration during fluidized bed combustion of biomass: A review, Fuel 2018, 230: 452-473. Doi: 10.1016/j.fuel.2018.04.098

Liu Z, Zhang T, Zhang J, Xiang H, Yang X, Hu W, Liang F, Mi B. Ash fusion characteristics of bamboo, wood and coal. Energy 2018, 161: 517-522. https://doi.org/10.1016/j.energy.2018.07.131

DIRECTIVE (EU) 2015/2193 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL of 25 November 2015

on the limitation of emissions of certain pollutants into the air from medium combustion plantshttps://eur-lex.europa.eu/legal-content/EN/TXT/?uri=CELEX:32015L2193.

Salmenoja K, Field and Laboratory Studies on Chlorine-induced Superheater Corrosion in Boilers Fired with Biofuels, Åbo Akademi, 2000, Faculty of Chemical Engineering, Process Chemistry Group. ISBN: 9521206195, 9789521206191.

Vamvuka D, Pitharoulis M, Alevizos G, Repouskou E, Pentari D. Ash effects during combustion of lignite/biomass blends in fluidized bed, Renewable Energy 2009, 34: 2662–2671. https://doi.org/10.1016/j.renene.2009.05.005

Gelecek

23 Ocak 2023

Lisans

Lisans